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Published 22:01 19 Sept 2017 BST
The couple met in 2007 on the set of film Jumper and got engaged in 2008.
This isn't the first time they've parted ways - they called off their engagement in 2010, only to get back together three months later.
They never married, though Rachel gave birth to the couple's daughter Briar Rose in October of 2014.
The pair maintained a low profile during their relationship and supported the No Kids Policy, a coalition to protect children of celebrities from being photographed without consent, according to CBS.
The most recent photo that the couple shared is a throwback on that Rachel posted to her Instagram account in April.
https://www.instagram.com/p/BTKZehTAqKd/?taken-by=rachelbilson
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